CHEMREX INC -- PL PREMIUM ADHESIVE, 73-948  -- 8040-00N082450
<pre>=====================  Product Identification  =====================

Product ID:PL PREMIUM ADHESIVE, 73-948
MSDS Date:08/01/1993
FSC:8040
NIIN:00N082450
=== Responsible Party ===
Company Name:CHEMREX INC
Address:889 VALLEY PARK DR
City:SHAKOPEE
State:MN
ZIP:55379
Country:US
Info Phone Num:612-496-6000
Emergency Phone Num:612-496-6000;800-424-9300(CHEMTREC)
CAGE:CHEMR
=== Contractor Identification ===
Company Name:CHEMREX INC
Address:889 VALLEY PARK DR
City:SHAKOPEE
State:MN
ZIP:55379
Country:US
Phone:612-496-6000/612-496-6027
CAGE:CHEMR
Company Name:CHEMREX INC
Address:6120 E 58TH AVE
Box:City:COMMERCE CITY
State:CO
ZIP:80022
Country:US
Phone:303-289-5286
CAGE:CHMRX

=============  Composition/Information on Ingredients  =============

Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (HYDROTREATED LIGHT
    PETROLEUM DISTILLATE).  VP: <1 @ 20C.  LEL: 1.6%.
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: 7-12%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA QUARTZ).  VP: NONE. 
    LEL: NONE.
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 0.01-1%
OSHA PEL:N/K 
ACGIH TLV:0.1 MG/M3 RDUST

Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC
    (HYDROUS MAGNESIUM SILICATE)).  VP: NONE.  LEL: NONE.
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 15-40%
OSHA PEL:20 MPPCF
ACGIH TLV:2 MG/M3 RDUST

Ingred Name:POLYMETHYLENEPOLYPHENYL ISOCYANATE.  VP: <0.0001 @ 20C. 
    LEL: NONE.
CAS:9016-87-9
RTECS #:TR0350000
Fraction by Wt: 4-8%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (METHYLENE
    BISPHENYL DIISOCYANATE) (SARA 313).  VP: <1 @ 20C.	LEL: 1%.
CAS:101-68-8
RTECS #:NQ9350000
Fraction by Wt: 7-12%
OSHA PEL:0.02 PPM, C
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:VOLATILE ORGANIC COMPOUND: 122 G/L OR 1.02 LBS/GAL,
    EXCLUDING WATER AND EXEMPT COMPOUNDS
RTECS #:9999999VO
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT: SWALLOWED. CHRONIC:PROD DOES NOT CNTN DUST AS
    PRDCED & DOES NOT GENERATE DUST IN NORM USE. DUST GENERATED(ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: BY ABNORM ACTIVITIES SUCH AS SANDING/GRINDING, COULD
    CNTN TRACE AMT OF FREE, RESPIRABLE SILICON DIOIXDE (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: (QUARTZ); PRLNGD &/OR RPTD OVEREXP MAY CAUSE
    SILICOSIS/OTHER DELAYED & SERIOUS LUNG INJURY. PROD CNTNS A (ING
    10)
RTECS #:9999999ZZ

Ingred Name:ING 9: SOLV (HYDROTREATED PETRO DISTIL). RPTS ASSOC RPTD &
    PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: SYS DMG. SOLVS ALSO REPORTED TO CAUSE LIVER DMG,
    KIDNEY DMG, MUC MEMB IRRIT. BE WARNED THAT INTENTIONAL (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: MISUSE BY DELIB INHAL CONTENTS ("SNIFFING") MAY BE
    HARMFUL/FATAL. PROD CNTNS ISOCYANATE. PRLNGD/RPTD (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: EXPOS TO ISOCYANATES CAN LEAD TO SKIN SENSIT. FOR
    PERS SENSITIZED TO EVEN BRIEF EXPOS TO ISOCYANATE CAN (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: PRDCE REDDENING, SWELL, RASH/BLISTERS. SIMILARLY,
    PRLNGD & RPTD EXPOS CAN LEAD TO RESP SENSIT. IN SUCH (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: PERS BRIEF EXPOS TO ISOCYANATES AT LEVELS WELL
    BELOW TLV CAN PRDCE CHEM ASTHMA & NONSPECIFIC ASTHMATIC CNDTNS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: MOVE VICTIM TO FRESH AIR. IF VICTIM HAS
    DFCLTY BRTHG, GIVE OXYGEN. ADMINISTER ARTF RESP IF NOT (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: BRTHG. OBTAIN IMMED MED ATTN. INGEST: OBTAIN IMMED
    MED ATTN. DO NOT INDUCE VOMIT. SHOULD VOMIT OCCUR, (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: BE SURE TO KEEP VICTIM'S HEAD BELOW HIPS TO AVOID
    ASPIRATION OF VOMITUS INTO LUNGS.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: SEWER OR SOAK UP W/INERT ABSORB. DO NOT
    DISCHARGE PROD OR WASTE WATER TO LAKES, STREAMS, PONDS OR (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: SEWER. AVOID CONTACT W/EYES & SKIN. REPORT SPILL TO
    APPROPRIATE AUTHORITIES.
RTECS #:9999999ZZ

Ingred Name:PROT GLOVES: SUPPORTED PVA OR NITRILE GLOVES. AVOID
    NEOPRENE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: MOD IRRITANT. MAY CAUSE
    TEARING, REDDENING & REVERSIBLE CORNEAL INJURY. SKIN: REGARD PROD
    AS SEV IRRITANT. PROD CNTNS AN ISOCYANATE, A CLASS OF CMPDS
    GENERALLY REGARDED AS PRIMARY SKIN IR RITANTS. CNTCT W/PROD MAY
    CAUSE DERM, ALLERGIC RESPONSES & IN SENSITIVE INDIVIDUALS, REDNESS,
    SWELL & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONO,
    VOL 68, 1997:GROUP 1. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:ANTIC
    TO BE CARCIN.
Effects of Overexposure:HLTH HAZ: BLISTERS. INHAL: REGARD PROD AS SEV
    IRRITANT. PROD CNTNS ISOCYANATE. EXPOS TO CONC OF AIRBORNE
    ISOCYANATES ABOVE TLV MAY PRDCE IRRIT OF RESP TRACT, COUGH, CHEST
    DISCOMFORT, SHORTNESS OF BRTH . INDIVIDUALS W/HISTORY OF EXPOS TO
    ISOCYANATES CAN DEVELOP MORE SEV SYMPS SUCH AS BRONCH, BRONCH
    SPASMS & PULM (SUPDAT)
Medical Cond Aggravated by Exposure:ANY PRE-EXISTING RESPIRATORY OR
    SKIN CONDITION.

=======================  First Aid Measures  =======================

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LST 15 MIN. IF NEC,
    GENTLY HOLD EYELIDS OPEN DURING FLUSH. OBTAIN IMMED MED ATTN. SKIN:
    REMOVE CONTAMD CLTHG & SHOES. WASH AFFECTED AREAS THOROUGHLY W/SOAP
    & WATER . WIPE/FLUSH AFFECTED SKIN W/ISOPROPYL ALCOHOL (RUBBING
    ALCOHOL). WASH AGAIN THOROUGHLY W/SOAP & WATER TO REMOVE
    POLYETHYLENE GLYCOL & RESIDUAL PROD. IF SYMPS PERSIST, OBTAIN MED
    ATTN. INHAL: (ING 16)

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:230F,110C
Lower Limits:0.6%
Upper Limits:7.0%
Extinguishing Media:WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON
    DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
    CNTNRS EXPOSED TO FIRE SHOULD BE KEPT COOL W/WATER SPRAY. WATER
    STREAM DIRECTED INTO FIRE MAY CAUSE (SUPDAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE DUE TO BUILD UP
    OF PRESS WHEN EXPOS TO HEAT. THERMAL DECOMP/COMBUST OF PROD MAY
    GENERATE IRRIT &/OR TOX GASES. VAP IS HVR/AIR & (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENT AREA & REMOVE IGNIT SOURCES. EVACUATE
    UNNEC PERS. PUT ON NIOSH APPRVD RESP PROT. DIKE/IMPOUND SPILLED
    LIQ. COVER SPILL W/ABSORB. SWEEP/SHOVEL INTO CNTNRS. COVER LOOSELY
    & REMOVE TO APPROP WATER A REA. FLUSH SPILL W/EXCESS WATER TO
    CHEM(ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT BREATHE VAPORS. AVOID CONTACT
    WITH EYES, CLOTHING AND SKIN. KEEP CONTAINER CLOSED WHEN NOT IN
    USE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DO NOT TAKE INTERNALLY. WEAR PROTECTIVE CLOTHING AT
    ALL TIMES. WASH THOROUGHLY AFTER USING. USE ONLY WITH ADEQUATE
    VENTILATION.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATORY PROTECTION WHEN
    THE PRODUCT IS MIXED OR APPLIED IN A POORLY VENTILATED AREA OR IF
    WORKPLACE LEVELS OF INGREDIENTS EXCEED THE TLV. FOLLOW APPLICABLE
    FEDERAL, STATE AND L OCAL REGULATIONS.
Ventilation:USE LOCAL EXHAUST AS NEEDED TO KEEP VAPOR/DUST LEVELS BELOW
    RECOMMENDED LIMITS.
Protective Gloves:NATURAL OR BUTYL RUBBER, (ING 21)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
    CLEAN PROTECTIVE CLTHG TO COVER ARMS & LEGS & KEEP EXPOS TO
    MINIMUM.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EVAP RATE: SLOWER (RELATIVE TO N-BUTYL ACETATE). FIRE FIGHT PROC:
    FROTHING W/SUBSEQUENT SPREAD OF FIRE. EXPLO HAZ: MAY TRAVEL ALONG
    GROUND/FLOOR & BE IGNITED AT LOCATIONS DISTANT FROM SOURCE. EFTS OF
     OVEREXP: EDEMA (FLUID IN LUNGS). FOR MOST INDIVIDUALS THESE EFTS
    ARE REVERSIBLE. INGEST:MAY CAUSE IRRIT IF (ING 7)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:>480F,>249C
Vapor Pres:<1 @ 77F
Vapor Density:HVR/AIR
Spec Gravity:1.26
Evaporation Rate &amp; Reference:SUPDAT
Solubility in Water:SLIGHT (<0.1%)
Appearance and Odor:CLEAR VISCOUS LIQUID; MILD OILY ODOR.
Percent Volatiles by Volume:13-17

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, AMINES, STRONG OXIDANTS, STRONG BASES OR ACIDS.
Stability Condition to Avoid:CONTACT WITH WATER VAPOR. SOURCES OF
    IGNITION. LONG TERM EXPOSURE TO ELEVATED TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN,
    HYDROGEN CYANIDE GAS, OTHER ACID ACRID AND TOXIC FUMES.
Conditions to Avoid Polymerization:THIS PROD CONTAINS AN ISOCYANATE.
    CONTACT W/MOISTURE OR OTHER MATLS THAT REACT W/ISOCYANATES MAY
    CAUSE POLYMERIZATION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:REVIEW ALL LOCAL, STATE AND FEDERAL REGULATIONS
    CONCERING HEALTH AND POLLUTION FOR APPROPRIATE DISPOSAL PROCEDURES.
    DO NOT INCINERATE CLOSED CONTAINERS.

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