MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION -- 2-BUTOXYETHANOL -- 6810-00N011561
===================== Product Identification ===================== Product ID:2-BUTOXYETHANOL MSDS Date:04/06/1989 FSC:6810 NIIN:00N011561 === Responsible Party === Company Name:MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Other REC Limits:N/K OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 RAT ORAL 1480 MG/KG;LC50 (SEE SUPP) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:NIOSH STUDIES INDICATE 2-BUTOXYETHANOL HAS CAUSED REPRODUCTIVE DISORDERS IN LAB ANIMALS (RATS OR MICE) & MAY HAVE THE POTENTIAL FOR CAUSING SIMILAR DISORDERS IN HUMANS .LIQUID MAY DAMAGE THE EYE S,PRODUCING PAIN AND INJURY TO THE CORNEA.CAN BE ABSORBED THROUGH THE SKIN.MAY AFFECT CENTRAL NERVOUS SYSTEM. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:VAPORS IRRITATE EYES;LIQUID MAY CAUSE DAMAGE,PAIN & INJURY TO CORNEA.SKIN:MAY CAUSE IRRITATION.TOXIC.ABSORPTION CAUSES SYMPTOMS SIMILAR TO INHAL.INGEST:HIGHLY TOXIC;SYMP SIMILAR TO INHAL.INHAL:TO XIC VAPORS IRRITATE NOSE/THROAT,CAUSE HEADACHE,NAUSEA,VOMITING,DROWSINESS,UNCONSCIOUSNESS,FORMATION OF DARK-RED URINE. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS,OR IMPAIRED LIVER,OR KIDNEY OR LYMPHOID SYSTEM FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:EYES:WASH W/ PLENTY OF H*2O FOR AT LEAST 15 MIN;LIFT LIDS OCCAS.GET MED ATTN IMMED.SKIN:IMMED FLUSH W/ PLENTY OF H*2O AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG/SHOES.CALL MD IMMED.INGEST:GET IMMED M ED ATTN.IF MD UNAVAILABLE,INDUCE VOM.GIVE 2 GLASSES OF H*2O.STICK FINGER DOWN THROAT.GIVE NOTHING BY MOUTH TO UNCON PERS.INH:MOVE TO FRESH AIR.NOT BRTHG-GIVE ARTF RESP;BRTHG DFCLT-GIVE O*2.CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:138F,59C Lower Limits:1.1% Upper Limits:12.7% Extinguishing Media:DRY CHEMICAL,ALCOHOL FOAM,CO*2.USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTRS COOL.SOLID STREAM OF WATER WILL SCATTER FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA W/ FULL FACEPIECE IN POS PRESS MODE,FULL PROT CLTHG.COOL FIRE-EXPOSED CONTRS W/ H*2O SPRAY.SOLID H*2O STREAM WILL SCATTER/SPREAD FIRE. Unusual Fire/Explosion Hazard:ABOVE FP,VAPOR-AIR MIX EXPLOSIVE W/IN FLAM LIMITS.VAP CAN FLOW TO DISTANT IGNIT SOURCE & FLASH BACK.HAZ DECOMP PROD:CO,CO*2,PEROXIDES.AUTOIGNIT TEMP:472F,244C. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA.REMOVE IGNIT SOURCES.PROT CLTHG & RESP PROT REQUIRED.CONTAIN & RECOVER LIQ WHEN POSS.HAZ WASTE:ATOMIZE IN RCRA APPRVD COMBUST CHAMBER OR ABSORB W/ VERMICULITE,SAND,EARTH,SIMILAR MATL FOR DIS P IN RCRA APPRVD FACILITY.DO NOT FLUSH TO SEWER. Neutralizing Agent:N/K ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE.OUTSIDE OR DETACHED STORAGE IS PREFERRED.INSIDE STORAGE SHOULD BE IN STANDARD FLAMMABLE LIQUIDS STORAGE ROOM/CABINET. Other Precautions:SEPARATE FROM OXIDIZING MATLS.NO SMOKING IN STORAGE/USE AREA.DO NOT BREATHE VAPOR.AVOID CONTACT WITH EYES,SKIN,CLOTHING.KEEP CONTAINER CLOSED.USE WITH ADEQUATE VENTILATION.KEEP AWAY FROM HEAT,SPARKS,F LAME.CONTACT LENSES SHOULD NOT BE WORN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED,WEAR NIOSH-APPROVED SUPPLIED-AIR,FULL-FACEPIECE RESPIRATOR;AIRLINED HOOD;OR SELF-CONTAINED BREATHING APPARATUS. Ventilation:LOCAL AND/OR GENERAL EXHAUST REC TO KEEP EXPOS BELOW LIMITS.LOCAL EXHAUST PREFERRED.REFER TO ACGIH INDUS VENT DOCUMENT. Protective Gloves:IMPERVIOUS Eye Protection:CHEM SFTY GOGGLES &/OR FULL FACESHIELD. Other Protective Equipment:IMPERVIOUS BOOTS,LAB COAT,APRON OR COVERALLS TO PREVENT SKIN CONTACT.MAINTAIN EYE WASH FOUNTAIN,QUICK-DRENCH FACILITIES. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.WASH THOROUGHLY AFTER HANDLING.WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health LD50-LC50 MIX:RAT INHALATION 450 PPM/4H;LD50 RABBIT SKIN 490 MG/KG.ROUTES OF ENTRY:INHALATION,SKIN,INGESTION . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:340F,171C Melt/Freeze Pt:M.P/F.P Text:-94F,-70C Decomp Temp:Decomp Text:N/K Vapor Pres:0.6 MMHG Vapor Density:4.07,AIR=1 Spec Gravity:0.903 (WATER=1) Evaporation Rate & Reference:0.07 Solubility in Water:COMPLETE Appearance and Odor:CLEAR,COLORLESS LIQUID WITH SLIGHTLY ETHEREAL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS,ALKALIES MAY ATTACK METALLIC ALUMINUM AT HIGH TEMPERATURES. Stability Condition to Avoid:STABLE UNDER ORDINARY USE/STOR CNDNS.AUTO-OXIDATION MAY PRDCE PEROXIDES.HEAT,FLAME MAY ATTACK METALLIC AL AT HIGH TEMPS. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION.AUTO-OXIDATION MAY PRODUCE PEROXIDES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.